DFT-based calculations of silicon complex structures in the KF-KCl-K2SiF6 and KF-KCl-K2SiF6-SiO2 melts
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چکیده
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The redox chemistry of niobium(V) fluoro and oxofluoro complexes in LiF-NaF-KF melts
The electrochemical behavior of niobium(V) fluoro and oxofluoro complexes in eutectic LiF-NaF-KF (FLINAK) melts at 700°C has been studied by cyclic voltammetry. The fluoro complexes NbF, introduced into the melt by the addition of K2NbF7, can be reduced to niobium metal in two reversible steps involving one and four electrons, respectively. At 700°C the diffusion constants of the fluoro niobate...
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ژورنال
عنوان ژورنال: Journal of the Serbian Chemical Society
سال: 2019
ISSN: 0352-5139,1820-7421
DOI: 10.2298/jsc190225044v